Mandrake
In order to be green we would need the green pigment called chlorophyll. Chlorophyll absorbs light and uses it to turn the tissues of a plant a shade of green.
Photosynthesis is primarily performed in the leaves of a plant. This thus means we would need leaves. In Cassidy’s mind of jumbled craziness she imagines we would have leaves and vines for our hair...delightful isn’t it? However only having hair of leaves probably wouldn't provide enough energy to sustain our typically energetic lives. Having leaves anywhere else would just be weird so we would need to have some sort of new skin that had similar components to leaves. There’s also the possibility of having extra appendages and go all Avatar with an energy absorbing tail or something.
Also the Calvin cycle would need to be performed. In the Calvin cycle light is taken in. During a light reaction ATP and NADPH is changed into NADP* and ADP + PI. Basically light, water and Co2 is changed into Sugar and O2.
Because humans are humans there is a good chance there would be ethical problems. Nobody can put up with anything that is different and green humans would most certainly freak people out seriously. Cassidy keeps seeing this as an Avatar sort of situation where regular humans would power trip and be unaware of the harm they would cause to a new “species." If something is wrong, or regular humans see a problem. they would do anything in their power to “fix” it.
To Cassidy’s despair humans would still need to sleep. The cells in our bodies would still need to restore themselves even with various plant characteristics. All in all there a various forms we could take in order to become photosynthetic humans, and no one form is right.